Jewish tradition requires certain holy items that have to be written on parchment with kosher, opaque, black ink. These items are abbreviated, STAM, books of the Torah (Sifre Torah, in Hebrew), Philactaries (Tefillin in Hebrew), and Mezzuzos for the doorpost. To be kosher the ink must be made from kosher sources: plant matter, soot, water, and/or inorganic chemicals. That leaves a lot of options, and it is likely that black Sharpie would be kosher, at least after the fact. Ideally, the ink should wash off in water too, based on Numbers 5:23 (Also, Rambam, Hilchos Tefilin 1:4, and Shulchan Aruch, YD 271:6).
There are ancient recipes, and I decided to semi-follow one, using walnuts instead of the classic gall nut and copper vitriol instead of iron. The aim was an ink that’s dark, long lasting, compatible with animal-skin parchment, and dissolvable. Some vegetable inks rot or fade, and most iron-based inks become permanent, like paint, they do not re-dissolve in water. If you don’t want to go through all this, you can buy kosher iron ink, e.g. here, knowing that this ink isn’t ideal, but it’s the type most people use for the practical reason that it looks nicer and permanent is a comfort.
The classical recipes for STAM ink is based on using the shell of gall nuts, a tree-growth (not really a nut) found in the Mid-east. As an experiment, I’ve tried to make a respectable, kosher ink with walnuts instead. Walnut trees grow readily in the midwest. I collected a dozen walnuts with their husks from a tree near my home. The outer husk had been green originally, but had turned black by the time I picked them (mid November). Rather than extract the inner shell, I used the walnuts as I found them, and tried boiling them in denatured alcohol, and also in water. Boiling in alcohol didn’t work well, producing the weak ink shown below, left. Boiling in water (below right) produced a much darker liquid. I used this as the basis of my ink.
The traditional recipe begins by boiling gall nuts in water to produce a brownish ink-wash that looks hardly darker than my alcohol-wash ink. You then add soot and “green vitriol”. Perhaps that is copper sulphate, or perhaps iron sulphate. Copper sulphate is a dark blue, while iron sulphate is a light green. With gall nut water, it turns out that iron vitriol works ‘better’, reacting with tannin in the gallnut water to make a nice, black color that becomes a permanent ink. When tried the two types of vitriol with my walnut water, I saw no color advantage to iron over copper, and no real color change.
I put the walnuts in a beaker as shown, nearly covering them with water, and put a piece of foil on top. The longer I simmered the darker it got. In the end, I left the mix on a hotplate, on low for nearly a day as shown above. The ink-wash, by itself is a reasonably good ink, as shown below left.
The traditional recipe that I’ worked off o’m modifying includes three more ingredients, so I experimented with them. These were vitriol, soot, and gum Arabic, in proportions shown below, in the form of a poem in Arabic written about 900AD. The first of these additions I tested was vitriol. I first tried copper sulphate, half as much as walnut water, and found that it darkens the color a little and makes the combination a bit thicker thought the ink is still watery. Copper sulphate is an antimicrobial too, so even without changing the color much, I imagined this was a worthwhile addition. I also tried making the walnut ink with iron sulphate. This makes the ink slightly darker too, perhaps, but not thicker. I have less confidence about iron’s antimicrobial properties, and there were concerns that it could harm a parchment over time. I also worried that it would make the ink permanent.
The next ingredient was soot. It’s used to make the ink darker, and perhaps thicker. Traditional soot is made from burning olive oil. One collects the soot by placing a plate over the smoky oil fire. I tried a bit of this, but it was slow, and I had some chemically produced soot in my lab, bought from MER corp, leftovers from making buckminsterfullerene. I added as much soot as vitriol as in the poem below, and as expected found it increased the blackness of the ink. It also changed the texture, making the ink gritty and harder to write with. I had trouble dissolving the soot into the ink too, and apparently I’m not the first to have this trouble. Some suggested heating, and some suggested honey. I tried both, and heating helped more than honey. I also tried using a drop of dish soap. The result, above left, was blacker than the original, but the writing is not professional grade, IMHO. The ink does not write well, and it still doesn’t cover 100%. I moved on to the next ingredient, gum Arabica.

The mixing ratios in this poem are not exactly clear. The amount of soot is the same as of vitriol, and half that of gall, but is this the weight of the gall nuts, or volume, or the weight of the dried extract. I used volume of walnut water and volume of soot, and have the sense that this is too much soot. Also soot is messy and hard to dissolve; use gloves and a lab jacket. the soot does not come out easily.
My final ingredient is gum Arabic, the gum of the acacia tree. This seems to be used as a thickener. Gum Arabic is available in the US, on Amazon as an edible “candy”, so I bought some. It wasn’t expensive, but took about 10 days to get here. In the meantime, I tried honey as a thickener. It appears in some ancient recipes, but didn’t really help here, and left the page sort of sticky. Gum arabic is solider, so I hoped for for lasting product. When the Gum Arabic came, I found that it was solid, crystalline, with has hardly any taste. Maybe Arabs add sugar? I figure there might be a mystical advantage to gum Arabic since it comes from the Acacia tree, the type of tree used to make the Ark of the Covenant. My expectation was that it might also make the ink darker, and that it might help dissolve the soot.
As it happens, gum Arabic doesn’t dissolve in cold water. But it did dissolve in hot water if I mixed it in and stirred for 5 minutes. The gum helped dissolve the soot too; gum Arabic seemed to do a better job than honey in this respect. Once the gum ink dried it was nice and solid, with the dried letters standing off the page a bit; they’re raised letters, and I really like that. The ink was still sort of grainy, perhaps from the walnut bits. I then tried dipping a written on parchment into some water and found the ink-letters dissolved easily. My understanding is that the ink I’d made was highly kosher for STAM, but as a follow-up experiment, I’m carrying some inked parchment in my breast pocket to see if it rots or fades. So far, no change. Some samples of writing are at left. The upper words are with the iron-vitriol version (iron sulphate), the lower with the copper vitriol (copper sulphate). You can sense why scribes might prefer the iron ink.
Robert Buxbaum, December 22, 2024. Scribes of 2000 years ago used wooden pens, it seems, as feather quills and fountain pens hadn’t been invented. I used a wood pen on some samples above, made by carving a popsicle stick. The better-looking letters, and longer passages, were written with a metal, calligraphy “quill.”